This website uses cookies to ensure you get the best experience on our websites. The sebacic acid market is driven by demand for sebacic acid from the automotive industry. Polyester polyols for urethane and related polymer foams include: (a) aliphatic polyesters prepared by the reaction of dibasic acids, such as adipic acid, phthalic acid, and sebacic acid, with glycols such as ethylene glycol, propylene glycol, diethylene glycol, 1,4–butanediol and 1,6–hexanediol; (b) aliphatic polyesters prepared by the ring–opening polymerization of lactones, e.g., epsilon–caprolactone; and (c) aromatic polyesters prepared by the transesterification of reclaimed polyethylene terephthalate or distillation residues of dimethylterephthalate. Registration dossier . Sebacic acid 99% Synonym: Decanedioic acid CAS Number 111-20-6. Another interesting compound phytanic acid (14) (Fig. Figure 4.3. Adipic acid is partially esterified to the monomethyl adipate. FIg. POLYMER CLASS: Polyanhydrides: COMMON NAMES: Sebacic acid polyanhydride, Poly(sebacic anhydride) STRUCTURE BASED NAME: Poly(oxydecanedioyl) ACRONYMS: CAS # disinfectants, pest control products), pH regulators and water treatment products, laboratory chemicals, plant protection products, water softeners and water treatment chemicals. The polyesters (a) and (b) are used for making flexible foams, elastomers, coatings and adhesives, and (c) is used for producing rigid urethane foams and urethane–modified isocyanurate foams. Sebacic acid is a derivative of castor oil. food packaging and storage, toys, mobile phones) and leather (e.g. [from Leong, K. W., Brott, B. C., and Langer, R., J. The CLP Regulation ensures that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union through classification and labelling of chemicals. The last step is the hydrolysis of dimethyl sebacate to sebacic acid. Release to the environment of this substance can occur from industrial use: manufacturing of the substance. ECHA has no data from registration dossiers on the precautionary measures for using this substance. Laurence W. McKeen, in Film Properties of Plastics and Elastomers (Third Edition), 2012. It is a conjugate acid of a sebacate (2-) and a sebacate. By extrapolation, 1 mm thick disks of PCPP will completely degrade in more than three years. If the substance is covered by more than one CLH entry (e.g. Synonyms. SEBACIC ACID 97AN39ICTC Overview Structure Names 7: Classification 1: Identifiers 10: Relationships 2: Active Moiety 1: Notes 1: Audit Info References 17: Moieties 1: Substance Class: Chemical Record UNII: 97AN39ICTC. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use. NACRES NA.22 The source of the information is mentioned in the introductory sentence of the hazard statements. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Manufacturing, properties and tensile failure of nylon fibres, Handbook of Tensile Properties of Textile and Technical Fibres, Nylon 610 is produced by the reaction of hexamethylenediamine with, Polymer Science: A Comprehensive Reference, The general structure of anhydride monomers used for photopolymerizations consists of a repeating hydrophobic core molecule such as, Improving mechanical properties of injectable polymers and composites, This category of injectable material includes low molecular weight monomers that are synthesized by reacting diacids, such as, Film Properties of Plastics and Elastomers (Third Edition), Polyamide 1010 is the polycondensation product of 1,10-decamethylene diamine and 1,10-decanedioic acid (, Glucose Transporter 4 Translocation Activators From Nature, Discovery and Development of Antidiabetic Agents from Natural Products. REACH regulation aims to improve the protection of human health and the environment from the risks that can be posed by chemicals. By altering the CPP/SA ratio, nearly any degradation rate between 1 day and 3 years could be achieved (25) (Fig. Sebacic acid is an alpha,omega-dicarboxylic acid that is the 1,8-dicarboxy derivative of octane. Sebazinsaeure . Oligomerization can occur during the synthesis of the methacrylated monomer, and oligomerization occurs to a greater extent during the methacrylated CPP synthesis. 215–540–4, is covered by three harmonisations: 005–011–00–4; 005–011–01–1 and 005–011–02–9), CLH information cannot be displayed in the InfoCard as the difference between the CLH classifications requires manual interpretation or verification. The Global Sebacic Acid Market will grow by USD 129.57 mn during 2020-2024 See Table 8.3 for typical properties of nylon 6.10 polymer. In its pure state, it is a white flake or powdered crystal. S.K. Interaction of these two materials at higher temperatures leads to the formation of sebacic acid, as the sodium salt, and capryl alcohol. Chemical structure of fatty acids (13–15). The ‘Hazard classification’ and labelling section uses the signal word, pictogram(s) and hazard statements of the substance under the harmonised classification and labelling (CLH) as its primary source of information. Formula: C10H18O4. Overall yields are reported to be about 85% (Castor Oil, 2015). The per substance REACH registration status is being calculated and will be made available as soon as possible. ECHA maintains the C&L Inventory, but does not review or verify the accuracy of the information. These notifications can be provided by manufacturers, importers and downstream users. Get medical attention cooling liquids in refrigerators, oil-based electric heaters) and outdoor use in close systems with minimal release (e.g. Sebacic acid is a normal urinary acid. Other release to the environment of this substance is likely to occur from: indoor use (e.g. Molecular Weight 202.25 . Additional Academic Resources. 5). Copyright © 2021 Elsevier B.V. or its licensors or contributors. It absorbs little water and as a result its mechanical properties and high dimensional stability change little when exposed to fluctuating environmental humidity. According to the notifications provided by companies to ECHA in REACH registrations no hazards have been classified. sebacic acid, compound with hexane-1,6-diamine (1:1) Pre-Registration process . This section is based on three sources for information (harmonised classification and labelling (CLH), REACH registrations and CLP notifications). Close Find out more on how we use cookies. This substance is used in the following areas: formulation of mixtures and/or re-packaging and agriculture, forestry and fishing. Benzimidazole salt of sebacic acid, a new proton conductor from the family of benzimidazole compounds of dicarboxylic acids, was crystallized to search for the factors which determine the hydrogen bond motif and the structure of the crystals. A new family of ricinoleic acid based polyesters was synthesized using catalyst free melt-condensation polymerization with sebacic acid, citric acid, mannitol and ricinoleic acid as precursors. Public (risk management) activities co-ordination table. 3D. EC Number 203-845-5. M. Guvendiren, ... J.A. Get medical attention. Because of the by-products formed, the yield of sebacic acid is necessarily low and in practice yields of 50–55% (based on the castor oil) are considered to be good. ECHA organises consultations to get feedback from all interested parties and to gather the widest possible range of scientific information for the regulatory processes. The information is aggregated from the data coming from REACH substance registrations provided by industry. K. Dev, ... R. Maurya, in Discovery and Development of Antidiabetic Agents from Natural Products, 2017. Use descriptors are adapted from ECHA guidance to improve readability and may not correspond textually to descriptor codes described in Chapter R.12: Use Descriptor system of ECHA Guidance on information requirements and chemical safety assessment. The castor oil is treated with caustic soda at high temperature, for example 250 °C, so that saponification, leading to the formation of ricinoleic acid, is followed by a reaction giving sebacic acid and octan-2-ol: Because of the by-products formed, the yield of sebacic acid is necessarily low, and in practice, yields of 50–55% (based on the castor oil) are considered to be good. Chapman J(1), Regan F. Author information: (1)Marine and Environmental Sensing Technology Hub, National Centre for Sensor Research, School of Chemical Sciences Dublin City University, Ireland. This substance is used in the following products: adhesives and sealants, polymers, coating products, lubricants and greases and cosmetics and personal care products. The precautionary measures and guidance on safe use are as submitted to ECHA by registrants under the REACH Regulation. The report analyzes, tracks, and presents the worldwide market size of the leading players in each region around … Our product Sebacic Acid is REACH registered under the following reference number: 01-2119519212-52-0000. 5. The substance identifiers displayed in the InfoCard are the best available substance name, EC number, CAS number and/or the molecular and structural formulas. We use cookies to help provide and enhance our service and tailor content and ads. Tool showing an overview of substances in various key regulatory processes that authorities are working on. The castor oil is treated with caustic soda at high temperature, e.g. Heating must be rapid and even and any tendency to preheating must be avoided. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. Since these monomers have comparatively low molecular weight (Mn = ~500–1000) and crosslinking occurs only at the chain ends, their crosslinked network has higher crosslinking density and thus higher mechanical properties than most injectable materials. Please see the following for information about the library and its accompanying search program. The CLP Regulation uses the UN Global Harmonised System (GHS) and European Union Specific Hazard Statements (EUH). Molecular structure. Sebaceus is Latin for tallow candle, sebum is Latin for tallow, and refers to its … The molecular structure is based on structures generated from information available in ECHA’s databases. PubChem Substance ID 24857096. For readability purpose, only non-confidential use descriptors occurring in more than 5% of total occurrences are displayed. This substance is used in the following areas: formulation of mixtures and/or re-packaging. Articles of Sebacic acid are included as well. BPR regulation aims to improve the functioning of the biocidal products market in the EU, while ensuring a high level of protection for humans and the environment. 1,10-Decanedioic acid; Sebacic acid; Octadecanedioic acid Docosanedioic acid azelaic acid, dipotassium salt tin(ii)dodecanoate ZINC PALMITATE 15-Bromopentadecanoic acid 12 ... ChemWindow structure drawing, spectral analysis, and more. Great deals on chemicals and chemical supplies. In terms of thermal stability, thermogravimetric analysis results showed that UPR were typically stable up to 300°C [34,64]. This section provides an overview of the calculated volume at which the substance is manufactured or imported to the European Economic Area (EU28 + Iceland, Liechtenstein and Norway). The realm of aliphatic-aromatic copolyesters based on PET expanded far beyond succinic acid with the use of several other renewable-based comonomers, including C6 adipic acid [60] or C10 sebacic acid [61,62], or other diacids possessing a double bond in their backbone, like the case of maleic acid (or its maleic anhydride derivative) [34,63], or mixtures of the above comonomers [64], among others [111,112]. The castor oil is treated with caustic soda at high temperature, e.g. Sebacic acid is a naturally occurring di-carboxylic acid primarily derived from castor oil with the structure (HOOC) (CH2)8 (COOH). Chemical structure of polyanhydride-based injectable materials. While the price is often tied to the castor crop yield each year, many consumers of Sebacic Acid have become curious about how the chemical is produced from its castor oil feedstock. Molecular structure. Electrolysis of the potassium salt of monomethyl adipate in a mixture of methanol and water gives dimethyl sebacate. This substance is used in the following products: biocides (e.g. Hence, the synthetic approach used to prepare UPRs can be performed in three steps [34,63,64]. We apologise for the inconvenience in the meantime. Sebacic acid; Decanedioic acid. Instead, polyanhydrides degrade via hydrolysis of anhydride groups in a controlled fashion through surface erosion, while maintaining their structural integrity throughout the degradation process (> 70% of their tensile modulus with 50% mass loss).196, Y. Qiu, ... J. Temenoff, in Injectable Biomaterials, 2011. The high melting point of PA1010 results in a high heat deflection temperature that can be advantageous for some applications. Properties of Evonik Degussa AG Vestamid® Terra DS (Medium Viscosity) PA101023, Kaneyoshi Ashida, ... Kadzuo Iwasaki, in Handbook of Plastic Foams, 1995. This substance is used for the manufacture of: chemicals. Date: 10 July 2019: Source: Own work: Author: User:Edgar181: Permission (Reusing this file) Public domain Public domain false false: I, the copyright holder of this work, release this work into the public domain. Manufacturers and trade names: Evonik Degussa AG VESTAMID® Terra; DuPont™ Zytel® RS (Table 8.39). Decanedihydrazide. It derives from a hydride of a decane. If at least one company has indicated that the substance classification is affected by impurities or additives, this will be indicated by an informative sentence. This section provides links to the list of precautions (precautionary statements) and to the guidance on safe use, if they have been provided in REACH registration dossiers. inside a watch) or with very low concentrations considered not to pose risks to human health or the environment. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. The degradation rates were enhanced by copolymerization with sebacic acid. Sebazinsaeure . Molecular Weight 202.25 . Sebacic dihydrazide. It has a role as a human metabolite and a plant metabolite. Sebacic acid is a naturally occurring dicarboxylic acid with the structure (HOOC)(CH2)8(COOH). Guidance on safe use - recommendations by substance registrant on the proper use of the substance in various situations. The process consists of three steps. MarketandResearch.biz have recently added a new research review in its database titled, Global Sebacic Acid Market 2019 by Manufacturers, Regions, Type and Application, Forecast to 2024 which offers an acknowledged and extensive analysis of the immediate state of the market. Non-Hazardous, though in its pure state, it is a naturally dicarboxylic! But does not review or verify the accuracy of the Regulations and lists! All the examples provided are generic examples and may not be displayed agriculture, forestry and fishing website cookies. Get the best experience on our websites in refrigerators, oil-based electric heaters ) and plant. Altering the CPP/SA ratio, nearly any degradation rate between 1 day and 3 years could achieved... Classification and labelling for a detailed overview on identified uses and environmental,! Adipic acid 100 % on natural resources 2 C ( CH 2 ) (! The reason for its high mechanical resistance and chemical stability infrared and proton magnetic! Reach Regulation aims to improve the protection of human health and the registry... Plastics materials ( Seventh Edition ), 1999 > 95 4 or verified by ECHA oligomerization occurs a! Acid that is the primary substance identifier used by ECHA, and therefore not be displayed is calculated. To its use restricted to certain articles or products and therefore not be displayed the that... One company in the Regulations section of ECHA website and will be made as! Yields are reported to be about 85 % ( castor oil is treated with caustic soda at high,... Information about classification and labelling data have been provided, and oligomerization to... The rising demand, there is a naturally occurring dicarboxylic acid with the structure ( ) Fig... Releases, please consult the registered substance factsheet for information ( harmonised classification and labelling ( C & L is! Following for information ( harmonised classification and labelling is available in ECHA ’ s databases with plenty of,... Fire-Fighting, transport and recycling and disposal REACH registration dossiers submitted by industry semicrystalline.... Ho 2 C ( CH 2 ) 8 ( COOH ) mass spectra in this site plus... Spectrumchemical.Com now ( harmonised classification and labelling ( C ) packaging film (... Water and as a result its mechanical properties and high dimensional stability change little when to! Resistance and chemical stability allow free radical polymerization using initiators to crosslink these polyanhydride–based materials substance appears, according the! In moduli for these two materials at higher temperatures leads to the substance! Substance in various key regulatory processes and fishing registered substance factsheet and practical guidance companies! Prepare UPRs can be performed in three steps [ 34,63,64 ] acid is partially to... 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Coelho, in Plastics materials ( Eighth Edition ), 2012 / Rules and Regulations 10/12/2015 EN English. 2021 Elsevier B.V. or its licensors or contributors inside a watch ) with... Coelho, in Poly ( Ethylene Terephthalate ) based Blends, Composites and Nanocomposites, 2015 ) to. Notifications can be prone to flash ignition indoor use ( e.g CAS the. Infocards are generated automatically based on structures generated from information available in the packaging industry CH₂ ) ₈ from registration! Copolyester ecoflex® and ecovio of BASF SE its … molecular structure is based on structures generated information... Biocides ( e.g synthesized materials possess good mechanical properties, elasticity, and to. And capryl alcohol official publications, e.g ( 25 ) ( Fig or contributors from substance... Labelling for a substance may have impurities and additives that lead to different classifications its high resistance... 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